The selective activation of methane (CH4) by chemical catalysts (i.e. energy utilization by means other than combustion) is a widely sought after goal. The Rose group seeks to develop novel catalysts and ligand systems for both CH4 and carbon dioxide (CO2) activation. Our strategy is to explore the hard-soft interactions between heavy main-group atoms (As, Sb, Bi) and first-row metals (Mn, Fe, Co, etc). The synthesis and investigation of the fundamental properties of these molecules (magnetic, spectroscopic, reactivity) is the goal of this project. Students interested in molecular organic/inorganic syntheses and spectroscopy are encouraged to apply.
Prerequisite: One year organic chemistry (lecture & lab)
Preferred: CH 431, Inorganic chemistry (lecture & lab)
Project-oriented approach
The applicant must be available both Fall and Spring semesters.
Availability during Summer is required.
Attendance of weekly group meetings (1-2 hours).
Research Units given commensurate with labwork.
No monetary stipend available.
Assist graduate student & postdoc led research.
Preparative synthesis of main group element ligands.
Metalation of main group ligands with transition metals
Routinely perform and interpret spectroscopic characterization (IR, NMR, UV/vis)
Opportunity for independent senior research upon outstanding performance in lab.
